MSDS Information
SECTION 1: IDENTIFICATION
1.1. Product Identifier
Product Form: Article
Product Name: All Castlebar Cemented Tungsten Carbide and Cermet Tools
Synonyms: Carbide Cutting Tools
1.2. Intended Use of the Product
Use of the substance/mixture:
No additional information available
1.3. Name, Address, and Telephone of the Responsible Party
Company:
Castlebar Corporation
406 15th St SW
Canton, OH 44707-4011
T: 330-451-6511
www.castlebar.us
1.4. Emergency Telephone Number No additional information available
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
Classification (GHS-US)
Within the meaning of the OSHA Hazard Communication Standard [29 CFR 1910.1200]: this product
is considered a manufactured article and is not considered a hazard when used in a manner which
is consistent with the labeled directions.
2.2. Label Elements
GHS-US Labeling
No labeling applicable
2.3. Other Hazards
During normal operation and usage, cemented carbide products do not present inhalation, ingestion, or
other chemical hazards. However, operations such as grinding, cutting, burning, and welding of such
products may release dusts, fumes, or vapors which may present health hazards. The health hazards
described below relate to these non-routine operations, as well as exposure to component materials.
Wet or dry grinding of cemented carbide products will produce dusts of potentially hazardous ingredients
which can be inhaled, swallowed, or come in contact with the skin or eyes. During wet grinding, the dust
can be suspended or dissolved in the coolant mist.
2.4. Unknown Acute Toxicity (GHS-US)
No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
Not applicable
3.2. Mixture
|
Name
|
Product Identifier
|
%
|
Classification (GHS-US)
|
|
Tungsten carbide
|
(CAS No) 12070-12-1
|
10 - 94
|
Not classified
|
|
Titanium carbide (TiC)
|
(CAS No) 12070-08-5
|
0.2 - 53
|
Not classified
|
|
Cobalt
|
(CAS No) 7440-48-4
|
0 - 20
|
Acute Tox. 4 (Oral), H302
Acute Tox. 1
(Inhalation:dust,mist), H330
Resp. Sens. 1B, H334
Skin Sens. 1, H317
Carc. 2, H351
Repr. 2, H361
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
|
|
Nickel
|
(CAS No) 7440-02-0
|
0 - 15
|
Skin Sens. 1, H317
Carc. 2, H351
STOT RE 1, H372
Aquatic Chronic 3, H412
|
|
Tantalum carbide (TaC)
|
(CAS No) 12070-06-3
|
0 - 15
|
Not classified
|
|
Niobium carbide (Nb2C)
|
(CAS No) 12011-99-3
|
0 - 5
|
Not classified
|
|
Chromium
|
(CAS No) 7440-47-3
|
0 - 3
|
Comb. Dust, h332
|
|
Chromium carbide (Cr3C2)
|
(CAS No) 12012-35-0
|
0 - 3
|
Not classified
|
|
Aluminum oxide
|
(CAS No) 1344-28-1
|
0 - 2
|
Not classified
|
|
Boron oxide (B2O3)
|
(CAS No) 1303-86-2
|
0 - 2
|
Repr. 1B, H360
|
|
Zirconium
|
(CAS No) 7440-67-7
|
0 - 2
|
Pyr. Sol. 1, H250
Self-heat. 1, H251
Water-react. 1, H260
|
|
Molybdenum
|
(CAS No) 7439-98-7
|
0 - 2
|
Comb. Dust, H232
|
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
4.1. Description of First Aid Measures
First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel
unwell, seek medical advice.
First-aid Measures After Inhalation: When symptoms occur: go into open air and ventilate suspected
area. Obtain medical attention if breathing difficulty persists.
First-aid Measures After Skin Contact: Wash with plenty of soap and water. Obtain medical
attention if irritation develops or persists.
First-aid Measures After Eye Contact: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
First-aid Measures After Ingestion: If substantial quantities are swallowed, dilute with large
amount of water. Induce vomiting and seek medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: None expected under normal conditions of use.
Symptoms/Injuries After Inhalation: Dust from this product may cause irritation to the respiratory tract.
Symptoms/Injuries After Skin Contact: Dust may cause irritation in skin folds or by contact in
combination with tight clothing.
Skin exposure can cause an allergic red rash (cobalt itch).
Symptoms/Injuries After Eye Contact: Eye contact with dust may cause mechanical irritation.
Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects.
Chronic Symptoms: Chronic exposure to respirable dust containing cobalt and tungsten carry the
potential to cause permanent respiratory diseases, including occupational asthma, interstitial
pneumonitis and fibrosis (hard-metal disease), and emphysema. Symptoms include productive
cough, wheezing, dyspnea (upon exertion), pleuritic chest pain, and weight loss. Reports outside
the industry suggest that ingestion of significant amounts of cobalt can cause blood, heart, and
other organ effects. Cobalt metal with tungsten carbide is listed by IARC as Group 2A - probably
carcinogenic to humans. Nickel is listed by IARC as Category 2B possibly carcinogenic to humans.
Cobalt is listed by ACGIH as an animal carcinogen (A3). Cobalt and nickel are known to the State
of California to cause cancer. Nickel is considered reasonably anticipated to be a carcinogen by NTP.
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
If medical
advice is needed, have product container or label at hand.
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media: Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of
water may spread fire.
5.2. Special Hazards Arising From the Substance or Mixture
Fire Hazard: Not considered
flammable but may burn at high temperatures.
Explosion Hazard: Dusts may present a fire or explosion hazard under rare favoring conditions
of particle size, dispersion, concentration, and strong ignition source. However, this is not expected
to be a problem under normal handling conditions.
Reactivity: Hazardous reactions will not occur under normal conditions.
5.3. Advice for Firefighters
Precautionary Measures Fire: Exercise caution when fighting any chemical fire.
Firefighting Instructions: Do not breathe fumes or vapors from fire.
Protection During Firefighting: For a dust fire confined to a small area, use a respirator approved
for toxic dusts and fumes. For a large fire involving this material, fire fighters should use a self-contained
breathing apparatus.
Other Information: Refer to Section 9 for flammability properties.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1.Personal Precautions, Protective Equipment and Emergency- Procedures
6.1.1. For Non-emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
6.1.2. For Emergency Responders
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Eliminate ignition sources. Ventilate area.
6.2. Environmental Precautions
Prevent entry to sewers and public waters.
6.3. Methods and Material for Containment and Cleaning Up
For Containment: Contain and collect as any solid.
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Avoid actions that
cause dust to become airborne during clean-up such as dry sweeping or using compressed air. Use
HEPA vacuum or thoroughly wet with water to clean-up dust. Use PPE described in Section 8. Transfer
spilled material to a suitable container for disposal.
6.4. Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection. Concerning
disposal elimination after cleaning, see item 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Additional Hazards When Processed: Use care during processing to minimize generation of dust. Avoid dust
production that exceeds permissible exposure limits.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands
and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work.
7.2. Conditions for Safe Storage, Including Any Incompatibilities
Storage Conditions: Store in a dry,
cool and well-ventilated place.
7.3. Specific End Use(s) No additional information available
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
For substances listed in section 3 that are not listed here, there are no established exposure limits from the
manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL),
or OSHA (PEL).
|
Aluminum oxide (1344-28-1)
|
|
|
USA ACGIH
|
ACGIH TWA (mg/m³)
|
10 mg/m³
|
|
USA OSHA
|
OSHA PEL (TWA) (mg/m³)
|
15 mg/m³ (total dust)
5 mg/m³ (respirable fraction)
|
|
Boron oxide (B2O3) (1303-86-2)
|
|
|
USA ACGIH
|
ACGIH TWA (mg/m³)
|
10 mg/m³
|
|
USA NIOSH
|
NIOSH REL (TWA) (mg/m³)
|
10 mg/m³
|
|
USA IDLH
|
US IDLH (mg/m³)
|
2000 mg/m³
|
|
USA OSHA
|
OSHA PEL (TWA) (mg/m³)
|
15 mg/m³ (total dust)
|
|
Chromium (7440-47-3)
|
|
|
USA ACGIH
|
ACGIH TWA (mg/m³)
|
0.5 mg/m³
|
|
USA ACGIH
|
ACGIH chemical category
|
Not Classifiable as a Human
Carcinogen
|
|
USA NIOSH
|
NIOSH REL (TWA) (mg/m³)
|
0.5 mg/m³
|
|
USA IDLH
|
US IDLH (mg/m³)
|
250 mg/m³
|
|
USA OSHA
|
OSHA PEL (TWA) (mg/m³)
|
1 mg/m³
|
|
Cobalt (7440-48-4)
|
|
|
USA ACGIH
|
ACGIH TWA (mg/m³)
|
0.02 mg/m³
|
|
USA ACGIH
|
ACGIH chemical category
|
Confirmed Animal Carcinogen with
Unknown Relevance to Humans
|
|
USA NIOSH
|
NIOSH REL (TWA) (mg/m³)
|
0.05 mg/m³ (dust and fume)
|
|
USA IDLH
|
US IDLH (mg/m³)
|
20 mg/m³ (dust and fume)
|
|
USA OSHA
|
OSHA PEL (TWA) (mg/m³)
|
0.1 mg/m³ (dust and fume)
|
|
Nickel (7440-02-0)
|
|
|
USA ACGIH
|
ACGIH TWA (mg/m³)
|
1.5 mg/m³ (inhalable fraction)
|
|
USA ACGIH
|
ACGIH chemical category
|
Not Suspected as a Human Carcinogen
|
|
USA NIOSH
|
NIOSH REL (TWA) (mg/m³)
|
0.015 mg/m³
|
|
USA IDLH
|
US IDLH (mg/m³)
|
10 mg/m³
|
|
USA OSHA
|
OSHA PEL (TWA) (mg/m³)
|
1 mg/m³
|
|
Zirconium (7440-67-7)
|
|
|
USA ACGIH
|
ACGIH TWA (mg/m³)
|
5 mg/m³
|
|
USA ACGIH
|
ACGIH STEL (mg/m³)
|
10 mg/m³
|
|
USA ACGIH
|
ACGIH chemical category
|
Not Classifiable as a Human Carcinogen
|
|
USA NIOSH
|
NIOSH REL (TWA) (mg/m³)
|
5 mg/m³
|
|
USA NIOSH
|
NIOSH REL (STEL) (mg/m³)
|
10 mg/m³
|
|
USA IDLH
|
US IDLH (mg/m³)
|
50 mg/m³
|
|
Molybdenum (7439-98-7)
|
|
|
USA ACGIH
|
ACGIH TWA (mg/m³)
|
10 mg/m³ (inhalable fraction)
3 mg/m³ (respirable fraction)
|
|
USA IDLH
|
US IDLH (mg/m³)
|
5000 mg/m³
|
8.2. Exposure Controls
|
Appropriate Engineering Controls
|
: Use local exhaust or general dilution ventilation or other
suppression methods to maintain dust levels below exposure
limits. Power equipment should be equipped with proper dust
collection devices. Ensure all national/local regulations are
observed.
|
|
Personal Protective Equipment
|
: Not generally required. The use of personal protective
equipment may be necessary as conditions warrant.
|
|
Materials for Protective Clothing
|
: Chemically resistant materials and fabrics.
|
|
Hand Protection
|
: Chemically resistant gloves are recommended,
but not required.
|
|
Eye Protection
|
: Chemical safety goggles.
|
|
Skin and Body Protection
|
: Wear suitable protective clothing.
|
|
Respiratory Protection
|
: If exposure limits are exceeded or irritation is experienced,
approved respiratory
protection should be worn.
|
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
|
Physical State
|
: Solid
|
|
|
|
Appearance
|
: Dark Gray
|
|
|
|
Odor
|
: Odorless
|
|
|
Odor Threshold
|
: No data available
|
|
|
pH
|
: No data available
|
|
|
Evaporation Rate
|
: No data available
|
|
|
Melting Point
|
: 5045 °C (9113 °F)
|
|
|
Freezing Point
|
: No data available
|
|
|
Boiling Point
|
: No data available
|
|
|
Flash Point
|
: No data available
|
|
|
Auto-ignition Temperature
|
: No data available
|
|
|
Decomposition Temperature
|
: No data available
|
|
|
Flammability (solid, gas)
|
: No data available
|
|
|
Vapor Pressure
|
: No data available
|
|
|
Relative Vapor Density at 20 °C
|
: No data available
|
|
|
Relative Density
|
: 10 - 15 (water=1)
|
|
|
Solubility
|
: Insoluble.
|
|
|
Partition Coefficient: N-Octanol/Water
|
: No data available
|
|
|
Viscosity
|
: No data available
|
|
|
|
|
|
|
|
9.2. Other Information No additional information available
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity: Hazardous reactions will not occur under normal conditions.
10.2. Chemical Stability: Stable at standard temperature and pressure.
10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
10.4. Conditions to Avoid: Not available
10.5. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Contact of dust with strong oxidizers may cause fire or explosion.
10.6. Hazardous Decomposition Products: Oxides of aluminum. Oxides of cobalt. Oxides of titanium. Oxides of tungsten. Carbon oxides (CO, CO2).
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information On Toxicological Effects Acute Toxicity: Not classified
|
Aluminum oxide (1344-28-1)
|
|
|
LD50 Oral Rat
|
> 15900 mg/kg
|
|
LC50 Inhalation Rat
|
> 2.3 mg/l/4h
|
|
Chromium (7440-47-3)
|
|
|
LD50 Oral Rat
|
> 5000 mg/kg
|
|
Cobalt (7440-48-4)
|
|
|
LD50 Oral Rat
|
215.9 - 1140 mg/kg
|
|
LC50 Inhalation Rat
|
> 10 mg/l (Exposure time: 1 h)
|
|
Nickel (7440-02-0)
|
|
|
LD50 Oral Rat
|
> 9000 mg/kg
|
|
Molybdenum (7439-98-7)
|
|
|
LD50 Oral Rat
|
> 2000 mg/kg
|
|
LD50 Dermal Rat
|
> 2000 mg/kg
|
Skin Corrosion/Irritation: Not classified
Serious Eye Damage/Irritation: Not classified
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Carcinogenicity: Not Classified
|
Chromium (7440-47-3)
|
|
|
IARC group
|
3
|
|
Cobalt (7440-48-4)
|
|
|
IARC group
|
2B
|
|
OSHA Hazard Communication Carcinogen List
|
In OSHA Hazard Communication Carcinogen list.
|
|
Nickel (7440-02-0)
|
|
|
IARC group
|
2B
|
|
National Toxicology Program (NTP) Status
|
Reasonably anticipated to be Human Carcinogen.
|
|
OSHA Hazard Communication Carcinogen List
|
In OSHA Hazard Communication Carcinogen list.
|
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: Dust from this product may cause irritation to the respiratory tract.
Symptoms/Injuries After Skin Contact: Dust may cause irritation in skin folds or by contact in combination with tight clothing.
Symptoms/Injuries After Eye Contact: Eye contact with dust may cause mechanical irritation.
Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects.
Chronic Symptoms: None expected under normal conditions of use.
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
|
Aluminum oxide (1344-28-1)
|
|
|
LC50 Fish 1
|
> 100 mg/l
|
|
EC50 Daphnia 1
|
> 100 mg/l
|
|
ErC50 (algae)
|
> 100 mg/l
|
|
NOEC (acute)
|
> 50 mg/l
|
|
Boron oxide (B2O3) (1303-86-2)
|
|
|
EC50 Daphnia 1
|
370 - 490 mg/l (Exposure time: 48 h - Species: Daphnia magna)
|
|
Nickel (7440-02-0)
|
|
|
LC50 Fish 1
|
100 mg/l (Exposure time: 96 h - Species: Brachydanio rerio)
|
|
EC50 Daphnia 1
|
13 (13 - 200) μg/l (Exposure time: 48h - Species: Ceriodaphnia dubia [static])
|
|
LC 50 Fish 2
|
1.3 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [semi-static])
|
|
EC50 Daphnia 2
|
1 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
|
|
EC50 Other Aquatic Organisms 2
|
0.174 (0.174 - 0.311) mg/l (Exposure time: 96 h - Species: Pseudokirchneriella subcapitata [static])
|
12.2. Persistence and Degradability No additional information available
12.3. Bioaccumulative Potential
|
Cobalt (7440-48-4)
|
|
|
BCF fish 1
|
(no bioaccumulation)
|
12.4. Mobility in Soil No additional information available
12.5. Other Adverse Effects
No additional information available
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations:
Dispose of waste material in accordance with all local, regional, national, and international regulations.
SECTION 14: TRANSPORT INFORMATION
14.1. In Accordance with DOT Not regulated for transport
14.2. In Accordance with IMDG Not regulated for transport
14.3. In Accordance with IATA Not regulated for transport
SECTION 15: REGULATORY INFORMATION
15.1 US Federal Regulations
|
Aluminum oxide (1344-28-1)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on
United States SARA Section 313
|
|
SARA Section 313 - Emission Reporting
|
1.0 % (fibrous forms)
|
|
Boron oxide (B2O3) (1303-86-2)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory
|
|
Chromium (7440-47-3)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on
United States SARA Section 313
|
|
SARA Section 313 - Emission Reporting
|
1.0 %
|
|
Chromium carbide (Cr3C2) (12012-35-0)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory
|
|
Cobalt (7440-48-4)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on
United States SARA Section 313
|
|
SARA Section 311/312 Hazard Classes
|
Immediate (acute) health hazard Delayed (chronic) health hazard
|
|
SARA Section 313 - Emission Reporting
|
0.1 %
|
|
Nickel (7440-02-0)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on
United States SARA Section 313
|
|
RQ (Reportable quantity, section 304 of EPA's List of Lists)
|
100 lb (only applicable if particles are < 100 µm)
|
|
SARA Section 311/312 Hazard Classes
|
Immediate (acute) health hazard
|
|
|
Delayed (chronic) health hazard
|
|
SARA Section 313 - Emission Reporting
|
0.1 %
|
|
Niobium carbide (Nb2C) (12011-99-3)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory
|
|
Tantalum carbide (TaC) (12070-06-3)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory
|
|
Titanium carbide (TiC) (12070-08-5)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory
|
|
Tungsten carbide (12070-12-1)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory
|
|
Zirconium (7440-67-7)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory
|
|
Molybdenum (7439-98-7)
|
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory
|
15.2 US State Regulations
|
Cobalt (7440-48-4)
|
|
|
U.S. - California - Proposition 65 - Carcinogens List
|
WARNING: This product contains chemicals known to the State of California to cause cancer.
|
|
Nickel (7440-02-0)
|
|
|
U.S. - California - Proposition 65 - Carcinogens List
|
WARNING: This product contains chemicals known to the State of California to cause cancer.
|
|
Aluminum oxide (1344-28-1)
|
|
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
|
|
Boron oxide (B2O3) (1303-86-2)
|
|
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
|
|
Chromium (7440-47-3)
|
|
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances
U.S. - Pennsylvania - RTK (Right to Know) List
|
|
Cobalt (7440-48-4)
|
|
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List
|
|
Nickel (7440-02-0)
|
|
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances U.S. - Pennsylvania - RTK (Right to Know) List
|
|
Tungsten carbide (12070-12-1)
|
|
U.S. - New Jersey - Right to Know Hazardous Substance List
|
|
Zirconium (7440-67-7)
|
|
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
|
|
Molybdenum (7439-98-7)
|
|
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
|
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date : 05/01/2015
Other Information : This document has been prepared in accordance with the SDS
requirements of the
OSHA Hazard Communication Standard 29 CFR
1910.1200.
GHS Full Text Phrases:
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Acute Tox. 1 (Inhalation:dust,mist)
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Acute toxicity (inhalation:dust,mist) Category 1
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Acute Tox. 4 (Oral)
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Acute toxicity (oral) Category 4
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Aquatic Acute 1
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Hazardous to the aquatic environment - Acute Hazard Category 1
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Aquatic Chronic 1
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Hazardous to the aquatic environment - Chronic Hazard Category 1
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Aquatic Chronic 3
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Hazardous to the aquatic environment - Chronic Hazard Category 3
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Carc. 2
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Carcinogenicity Category 2
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Comb. Dust
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Combustible Dust
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Pyr. Sol. 1
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Pyrophoric solids Category 1
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Repr. 1B
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Reproductive toxicity Category 1B
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Repr. 2
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Reproductive toxicity Category 2
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Resp. Sens. 1B
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Respiratory sensitisation Category 1B
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Self-heat. 1
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Self-heating substances and mixtures Category 1
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Skin Sens. 1
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Skin sensitization Category 1
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STOT RE 1
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Specific target organ toxicity (repeated exposure) Category 1
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Water-react. 1
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Substances and mixtures which in contact with water emit flammable gases Category 1
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H232
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May form combustible dust concentrations in air
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H250
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Catches fire spontaneously if exposed to air
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H251
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Self-heating: may catch fire
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H260
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In contact with water releases flammable gases which may ignite spontaneously
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H302
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Harmful if swallowed
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H317
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May cause an allergic skin reaction
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H330
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Fatal if inhaled
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H334
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May cause allergy or asthma symptoms or breathing difficulties if inhaled
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H351
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Suspected of causing cancer
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H360
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May damage fertility or the unborn child
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H361
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Suspected of damaging fertility or the unborn child
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H372
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Causes damage to organs through prolonged or repeated exposure
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H400
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Very toxic to aquatic life
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H410
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Very toxic to aquatic life with long lasting effects
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H412
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Harmful to aquatic life with long lasting effects
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This information is based on our current knowledge and is intended to describe the product for the purposes of
health, safety and
environmental requirements only. It should not therefore be construed as guaranteeing any
specific property of the product.
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